F338-Hukum 2 termodinamika ,perumusan Kelvin-Planck ,Clausius dan entropi
Hello hello
fans and physics lovers
this time I will explain about the
2nd law of thermodynamics
The first 2nd law of thermodynamics formulated by
Kelvin-Planck is about combustion engines it is
impossible to make an engine that draws
heat from high tendons and converts it
all into mechanical work So
if for example Here you have a
hot reservoir for example for a gasoline engine when it is
burned it will produce heat right Well
if this is all converted
into mechanical work it is impossible that
if it is possible like this wow this
can be perfectly economical Your engine so buy
1 liter of gasoline it is all burned into heat
all into mechanical work Well that is
very impossible yes Hi well
this is what is meant by
the laws of the thermometer the Kelvin-Planck formula
well what happens in nature is like
this a real engine is like this it
burns gasoline usually a combustion engine
here burns gasoline the calories that appear are
not all converted into
mechanical work some are also thrown out through the
exhaust
Is there a motorbike car that does not
have an exhaust it must have an exhaust
because the heat that is taken the heat that is
taken is not all Duba becomes
mechanical work but some are thrown out
through the exhaust that is the clear engine in
this world like this Well the second one is
Clausius's formula so the
thermohygrometer laws by Clausius are
about the cooling machine, it is impossible to
flow heat from low temperature to
high temperature without external effort
Hi so for example here there is a responsibility to
shoot this year this low element has a
high temperature which contains low calories
it must flow from high temperature to
lower temperature It cannot be
reversed from low to high
for example the temperature in your room is
successful Brazzers then the door is opened
it must be
hot air flowing from
your environment to the room and it cannot be reversed
like that so the heat flow is
naturally spontaneous from high temperature to
lower temperature for sure
hi why what if we for example
want to flow heat from low temperature
to high temperature it is possible but it must be
with external effort well this is what
was said earlier yes it is impossible to
flow heat from low temperature to
high temperature without me realizing outside Well
if there is external effort you can
flow heat from the lowest reservoir
to Syria higher for example this
is how a real cooling machine works
so a cooling machine for example AC
draws heat from inside the
cooled room to its environment which has a
higher temperature but that is with
electrical effort yes So if you have an
AC that is not plugged in,
you will not turn on the
electricity, it
will not cool your room, there is no heat
drained, the family temperature is
higher like that
Hi Well now 02.00 thermodynamics the
third formulation is about entropy
Nahin trophy the universe always increases
in an irreversible process and
there is always a Princess Belle process
Hi Well later I will explain what the
irreversible and reversible processes
Nahin trophy that I explained first what
is the intro Pi entropy is a measure of the
amount of heat energy that cannot be
converted into work for example in a
piston engine it will rub against
the cylinder Well if it rubs it
produces heat how much of the necklace
can be converted into work, it cannot,
instead the heat that appears is detrimental to the
work so the engine's work will be
reduced like that Because there is something that
turns into heat like that
Hi well then secondly there are
also those who define intropia
as the level of the system's energy state
the more energy it has, the
greater the entropy for example you
imagine there is a metal the
left end is very hot the right end is
very cold if the left end is very
hot while the right end is
very cold Well that means the energy is
localized like that from the heat
on the left The cold on the right Well that is
said to be not random energy but
over time it flows to Hi Sis Nur
flowing from the hot end to the
cold end finally the heat is evenly distributed if
the heat is evenly distributed it is said to be
random energy meaning the instructions are increasing like that
Well entropy can also be said
to be the level of disorder of the system
for example imagine there is a room filled with
30 students, the
students are studying comfortably,
suddenly the room is burned, what
happens then all the students will definitely run
helter-skelter the system is in a
more chaotic state like that
Sis maybe it is getting calmer when there is a
fire Wow never mind, yes, death is made by
that experience is impossible,
the students will definitely all spray out Well
that means the system is said to be
disordered and assume the students were
gas particles, yes, of course the refrigerator if
heated is also like that more
Wrong Behavior the system is said to be
increasingly disordered if it is increasingly
disordered then it is said that the entropy
increases like that Well if at a constant temperature the
entropy change that occurs
is delta Cipete how is Delta the
heat change that occurs while
teto is the temperature
well Delta es the entropy change is
always 0ad meaning
entropy The universe is always right
on the reversible process,
the reversible process is a process that can Bale
means the process can be returned
so that the
thermodynamic components
related to pressure, volume, temperature
can really be returned
to their original state
Hi, the reversible process is usually a
very slow process or a
quasistatic process,
so the quasistatic process means
the process that takes place at
any time can be said between the system
and its environment is in a state of
equilibrium.
This means that for example the temperature of the system
with distilled water is
very small, approaching North, as well as
the volume, pressure, and
so on, so the thermodynamic components
between the system and the environment are
the difference approaching Noor
Hi, the reversible process, for example,
is the Karno cycle process. Well, later
I will give an example of it, the process
in nature is of course naturally an
irreversible process, an irreversible process
is a process that cannot be returned
to its original state, cannot be reversed, well,
this will definitely cause an increase in
the entropy of the universe So the Delta es
will be greater than zero,
for example, you know, heat and heat is
always from what, from a high temperature to a
low temperature So if for example
you open the door of your room air-conditioned,
the heat must flow from
your environment to your room, right?
Hi Well, that's an irfal process, annoying
Hi and it can't be used, bro, it
can't be reversed, so for example, 6 back
from the heat flowing from your room
naturally out, that's impossible,
so in an irreversible process, the
entropy always increases, like only the
times, it also continues to increase, right, it ca
n't be reduced, for example, your age
continues to increase. It can decrease,
but I, so your age always increases, the
years always increase, finished in 2002,
2001, 2002, and the fun part is like that, right? Well,
like your age can divide 1920 and
so on, right? So, because
in an irreversible process, the instruction
always increases, the intropia of the universe
always increases, so it's said that
entropy is an arrow of time or
time error
Hi Well, I've explained this, right? The
Delta of the istir won't change.
Another tropical one is joule per Kelvin
and again, the change in heat in the
gas system, the unit is Jul, the change
is Suga, the unit is Kelvin
Hi Well, introverted with sub rubah, it
can also happen, so the Delta of the istir is the
change The entropy can be formulated as MJ
lonte2 one box or you can use the
molar heat capacity of the gas, namely Delta
snc lonte2 or this one I have already
explained Delta es still states
the change in entropy m is the mass Unit
kg is the specific heat of the gas Jere he is large
molar heat capacity of the gas daily one
only has mall T1 swagga while T2
is a gas end
Hi watch more clearly I will
give examples of questions example questions one by one
how much is the change in entropy of the gas system
in one cycle In the Kaho cycle, so it
becomes like this, it means
my intention is to have a PV diagram of the Karno cycle, it
is a cycle that is limited by two
isothermal processes and 2 adiabatic processes
or b is an isothermal expansion process,
heat enters the system,
for example Q1, well this is a
real shooting from a to b so later T1 is
greater than T2, you
can imagine At that time the temperature in the
engine is right, burn gasoline in the engine,
for example T2 is the temperature around the
exhaust Well if it works, it is a
shallow adiabatic expansion process, the jacket
is an isothermal compression process,
compression because it occurs volume decrease
yes if expansion occurs
volume increase well T2 is the low temperature
here in the impression process technical issue
heat will be removed from the gas system if
D in that direction is the compression process there is a
babis in the adiabatic process there is no
heat exchanged between the system
and the environment so Delta giginya is zero
here also Delta kynya is zero okay well in the
Karno cycle process it applies that the story of the
one box is equal to q22 If
you don't understand why this happens
Look at my previous video which
discusses the derivation of this formula
Well if we calculate how much
entropy change occurs in the
isothermal expansion process from a to b it
is the story to party one how much heat
is entered divided by shooting that is
this isothermal expansion process Well if in
this isothermal compression process If it is removed then
Delta scdd is Minaj 22 Why
minus because this heat is removed from the
gas system Well if the total entropy change
means Delta ESAB plus
scd data Delta sapi There is another
one party one Delta sdd is
wingki2 pete2 but the carnot cycle earlier
is ideal class yes it is reversible
Well so if infosebel Q1 box 1 =
qidu or two then I can replace this
yes Q2 pete 2 becomes q1pp one well
if I add the result is
zero because Delta es now means In
this Karno cycle there is a process that
Revo sebel the process can be reversed
hi okay example of the second question Ghazali
has a molar heat capacity of 12.5
joules per mole per Kelvin in a
constant volume process If
two moles of helium gas are heated without you buffer
realizing su-300 Kelvin becomes 500 Kelvin
calculate the change in entropy Well we
Answer yes Well the change in entropy
is ncv lonte2 per
t1n that is Mal from the suit yes this
occurs at constant volume so this
is the molar heat capacity of gas at
constant volume well
then we just enter the number the
moral is two cv 12.5 t2t one
I enter jebret the result is
12.7 7 juplret Kelvin this is the change in
entropy that occurs
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