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Termodinamika Kuliah 1 - Pendahuluan dan Konsep Dasar

49:56EnglishTranscribed Jul 19, 2026
0:00

Hello, welcome to the

0:01

thermodynamics course and this is the

0:03

first lecture which is about the introduction and

0:05

basic concepts So there are five contents that

0:08

we will discuss in this video in

0:10

this first lecture, the first we will

0:12

discuss the definition of thermodynamics and

0:14

its relationship to energy Then the

0:16

second we will discuss the system and

0:18

control volume, the third we will

0:20

discuss the properties of state and

0:22

equilibrium, the fourth we will

0:24

discuss what is the process and cycle, the

0:27

fifth we will discuss the zeroth law of

0:30

thermodynamics so in

0:31

this first lecture we will discuss more

0:33

Emm terms and also vocabulary that

0:36

we will use throughout the

0:38

thermodynamics lecture, yes Well here there is

0:40

one example in the picture on

0:42

the right, this is an example of the

0:45

application of thermodynamics, namely

0:47

Power

0:48

Plan or power plant, yes, so

0:51

thermodynamics is a

0:53

science that is actually very close

0:55

to our lives, so we will

0:57

discuss some important vocabulary and terms,

0:58

yes In this first lecture

1:01

Well, we will discuss from the term, yes,

1:04

or from the name of thermodynamics,

1:05

so thermodynamics can be

1:08

defined as the science of energy

1:11

So if statistics is the science

1:13

of data, yes, while thermodynamics

1:16

is the science of energy In essence we

1:19

discuss all forms of ee

1:22

energy changes, yes, it is a study

1:24

of thermodynamics, well, then from the

1:26

root of the word thermodynamics comes from

1:28

Greek, namely terme which

1:31

means heat or color and dynamic yes

1:35

or dynamis yes which means power, so

1:38

e thermodynamics is actually from the beginning of

1:41

e the development of human civilization, it is

1:45

a science that discusses the

1:48

conversion of heat

1:51

into power or work into power or

1:56

work, yes, One of the discoveries or

1:59

one of the tools that ee the first time

2:02

thermodynamics was used, it seems, is

2:04

ee the steam engine, yes, it converts heat

2:07

into power or work, which is

2:10

one of the markers of the

2:12

industrial revolution, well, what we will discuss throughout

2:14

eh the thermodynamics course

2:17

are the laws that are indeed the laws

2:19

of Thermodynamics, the

2:21

first is the first law, yes, the

2:23

first law of thermodynamics, this is

2:25

none other than the law of conservation of energy,

2:28

yes, and energy is a quantity or

2:31

property of thermodynamics, yes, And we

2:33

have studied together even in elementary school, yes, elementary school, junior high school,

2:35

high school about the law of

2:38

conservation of energy, yes, so if ee there is

2:41

one object above ee one height H,

2:46

yes, then he has

2:48

ee potential energy yes that is mgh yes

2:51

then he will change ee

2:53

this potential energy when the object

2:55

falls into kinetic energy yes 1/2 MV

2:59

p^ Well that is more or less the law of

3:02

conservation of energy yes in ee mechanics

3:05

Well here we will also discuss later the

3:06

first law of thermodynamics in

3:08

relation to the law of conservation of energy, namely the

3:11

relationship between work then there is heat

3:14

then there is internal energy yes

3:16

we have actually studied all of them in high school

3:17

but in thermodynamics in this lecture in

3:21

engineering we will deepen

3:23

from ee the law of conservation of energy

3:25

yes Well the first law of thermodynamics

3:28

deals more with the titas yes quantity quantity

3:31

while eh for

3:35

this second law discusses more about the quality of

3:39

energy Well this may be something that is still foreign to

3:42

our ears maybe yes when we

3:44

first studied thermodynamics e

3:46

in engineering or on campus or at

3:49

university yes that we will discuss the

3:51

quality of energy and not just

3:53

quantity yes so the second law of

3:54

thermodynamics will be related to

3:56

entropy yes E where the second law of

3:59

dynamics states that energy

4:02

not only has quantity but

4:05

also quality and the conditions for a process to

4:08

occur are that it takes place in a direction where

4:10

the quality decreases yes So it does not

4:13

increase so naturally ee energy

4:15

will flow from

4:17

higher quality to lower quality energy

4:19

yes For example, there is

4:21

one picture on the right side of

4:24

this slide yes there is one or a cup of

4:28

coffee yes if this is coffee

4:31

that may have just been served yes in a

4:33

cafe Let's say He has a temperature of 70

4:35

degrees Celsius yes Well 70 degrees

4:38

Celsius we can interpret this as

4:41

temperature yes if we put the temperature

4:43

there thermometer there we put the

4:45

temperature sensor yes it reads 70 degrees

4:47

Celsius yes Well this is one ee

4:51

quantity later yes quantity or

4:53

property we will study later namely ee

4:55

temperature but here of course there are

4:58

many ee water molecules yes water molecules

5:01

then there are many particles that

5:03

move and

5:05

EE this collective movement

5:08

causes the coffee to be hot yes Well

5:11

in this coffee there is energy yes Well

5:15

there is energy that will move to the

5:17

environment yes so if this cafe

5:19

Let's say it has air conditioning He has a temperature of 18

5:23

to 20 degrees Celsius then

5:25

the coffee itself is 70 degrees Celsius and

5:27

in our daily lives we

5:29

know that there will be a flow of heat yes

5:32

Q with the symbol q yes E there is a flow of

5:35

heat from this coffee to the environment in

5:39

this case is yes cafe So

5:43

if the first law of thermodynamics

5:45

states that in this coffee

5:47

there is energy, namely the quantity, the

5:50

second law of thermodynamics states

5:51

that there will be a flow of energy from

5:54

higher quality energy, namely

5:57

in this case coffee, yes, because its quality is

5:59

higher. It has a

6:02

higher quality and value ee compared

6:04

to the environment, yes, so there

6:06

will be a flow of heat, yes, from the

6:09

EE temperature is higher to the temperature is

6:12

lower or the quality is

6:14

higher to the quality is lower, yes,

6:17

why is it called a

6:18

higher quality, yes, because with

6:21

this 70 degrees Celsius heat, if we

6:23

convert it into work later with the

6:25

symbol W, yes, maybe it should be white

6:28

with the symbol w B, yes, then the work of 70

6:32

degrees Celsius will be much

6:34

greater than the 18 to 20

6:36

degrees Celsius, yes, and that is nothing other than

6:38

the principle of

6:40

thermodynamics itself, yes, namely converting

6:43

heat into power or work, the

6:45

higher the heat, the greater

6:47

or better we can

6:50

convert it into ee power or work, yes,

6:54

Well, the second law of thermodynamics states

6:56

that there will be a flow of heat and from

6:59

or there will be a flow of energy from the

7:01

higher quality to the

7:03

lower and Not on the contrary, yes,

7:05

for example,

7:06

Ee, we cannot heat this coffee to

7:10

70 degrees Celsius by taking

7:11

heat from outside. Is that right or not?

7:14

If, for example, Ee, we might

7:17

do it, then it is a violation, yes, if

7:20

someone says that, Okay, if I

7:22

have coffee at 70 degrees Celsius in

7:24

the environment or in a room that is 18

7:27

to 20 degrees Celsius, then I can

7:29

make

7:30

this temperature lower, let's say it

7:32

becomes 15 degrees Celsius, then

7:34

this 70 degrees Celsius rises, let's

7:36

say it becomes 75 degrees Celsius.

7:39

Well, this is a process that is

7:41

impossible in our

7:43

daily lives. Well, this process can be

7:45

done if we

7:47

add work from outside. Well, that is the

7:49

ee principles that

7:52

we will learn throughout

7:53

this course, yes, this is an

7:55

everyday example, but from this everyday example,

7:58

we can know that thermodynamics

8:00

is in our daily lives,

8:02

which we sometimes take for granted. Well,

8:04

hopefully after studying this, we will

8:06

no longer take it for granted, we will start

8:08

to think more deeply,

8:10

so we can study every

8:12

phenomenon that is around us and

8:14

can use it for applications in

8:16

our lives. Okay, let's continue the

8:19

study of thermodynamics. it is divided

8:21

into two, namely classical thermodynamics

8:24

which will be the discussion of

8:27

this course, yes, or in this video or in this

8:29

series of videos, yes, so

8:31

this course, yes, or this series of videos, if

8:34

you are not my students

8:37

who are ee enrolled or registered at

8:39

Unpar, yes, throughout the playlist of

8:41

this course, we will discuss only

8:42

classical thermodynamics, yes,

8:45

this classical thermodynamics is a

8:47

thermodynamic approach that does not

8:49

need to take into account the behavior of the

8:50

constituent particles, yes, So you could say that

8:53

this classical thermodynamics is a much

8:55

more

8:57

macroscopic study, yes, macroscopic, yes, for example,

9:01

we will calculate or yes, measure Yes,

9:04

if in the practicum in thermodynamics,

9:07

we will make measurements or

9:09

we calculate P, yes, which is

9:12

pressure, then there is another quantity, ee,

9:15

namely

9:16

volume, yes, then there is another one, namely

9:19

temperature, now this is the most frequent

9:21

quantity that we will calculate ee

9:25

in thermodynamics, yes, what is interesting

9:28

is There is a second study, namely

9:29

classical or statistical thermodynamics Oh,

9:32

sor, namely statistical thermodynamics, yes,

9:35

this second study,

9:36

statistical thermodynamics, is a

9:38

thermodynamic approach that takes into account the

9:41

average properties of the constituent particles, so It

9:43

can be said that

9:45

statistical thermodynamics is a

9:47

more microscopic study, yes. For example,

9:51

if in classical terminodynamics it

9:53

discusses pressure, yes, then in

9:58

statistical thermodynamics, yes, it discusses

10:01

pressure in the form of collisions between

10:03

particles, so let's say I have a

10:05

piston or a vessel, yes,

10:09

then I press it, yes, or

10:12

just a piston, yes, I press it, yes, here there is

10:16

a part that can press the

10:19

fluid, yes, then inside

10:20

here there is the fluid, yes, and in

10:23

the fluid, the liquid or gas, so this

10:25

can be a liquid or gas,

10:30

yes, the liquid and gas certainly

10:32

consist of atoms and molecules, right or

10:35

not, yes, Therefore, I give

10:38

an illustration here, yes, there are molecules

10:40

and atoms that EE, let's say it is a

10:44

gas or liquid, yes, and in

10:47

statistical thermodynamics, if we look at it in a

10:50

much more microscopic form of pressure,

10:53

yes, so if we press it, of course there

10:55

will be an increase in pressure, yes,

10:58

because I press it, I compress

11:01

it, yes, so the pressure increases, yes, the pressure increases,

11:04

the volume decreases, yes, and that is

11:07

a relation that we often use

11:08

in everyday life, so

11:10

the pressure increases, then the volume

11:13

will decrease, yes, And if I only

11:15

measure or calculate the pressure, then

11:18

I studying thermodynamics

11:20

classically but if I look at

11:23

each ee particle of course the

11:26

particle will move and will

11:28

start to press yes parts of

11:31

the wall right so if I

11:33

zoom in there is one molecule that starts to

11:35

press to the right ee Sori down

11:38

then there is a molecule that presses to

11:39

the right yes to the right wall then

11:42

there is a molecule that also presses up

11:44

because it starts to be pressed by part of the

11:46

piston then I calculate the

11:48

average here I calculate the average

11:50

of the collisions yes so the

11:53

average of the

11:57

collisions yes or ee momentum yes momentum

12:01

of the collisions yes Well this is what

12:04

will collectively

12:08

determine the pressure that we

12:10

calculate Okay so once again the

12:14

classical thermodynamics that we will

12:15

discuss throughout this course or

12:17

throughout this video playlist is

12:19

the macroscopic one yes which is the

12:22

result of the motion of the constituent particles

12:25

without having to take into account the

12:27

behavior of the particles so

12:30

we just calculate the p yes the pressure

12:32

or we just measure in experiments

12:34

for example without having to know that there are

12:36

how many particles EE

12:39

have collisions so much then

12:43

how many particles have e

12:45

momentum so much yes sor not collisions

12:47

should be momentum, yes, how much is it, right?

12:50

Well, while classical thermodynamics, yes,

12:52

we can make a graph here,

12:55

for example, there are a number of e particles,

12:59

here it should be, for example, momentum, yes, Ee

13:02

momentum, momentum p-nya P ee, meaning p

13:06

p momentum, yes, m * v, yes, then on the

13:09

y-axis there is the number of particles, yes,

13:12

of course it is not uniform, there are those with large e

13:16

momentum, then maybe

13:18

ee is in the middle of the value, then

13:20

there are also smaller ones, they are

13:22

higher, yes, this is eh, each

13:26

particle that we actually calculate

13:28

statistically How many particles

13:30

have a certain momentum, how

13:32

many particles have a

13:33

certain momentum, yes, then we take the

13:35

average and it turns out that this is actually

13:40

one entity or one quantity or one

13:43

property, later we will study it which is

13:45

called pressure, yes, so

13:47

our study is classical thermodynamics, yes,

13:50

hopefully this example can help What is the

13:52

difference between classical and statistical, okay, well,

13:55

next, we will probably

13:58

study together Later in

14:00

this course, there are applications of

14:01

thermodynamics, yes, and in

14:03

everyday life, we see this application,

14:05

the first is a refrigerator, yes,

14:08

this refrigerator, ee, transfers

14:10

heat, yes, transfers heat from the inside,

14:14

so transfers heat from inside yes

14:16

because if I have a drink that is EE

14:18

in room temperature or food in

14:19

room temperature I want to make it

14:22

cold yes and that means from hot

14:26

to cold yes now if you have

14:29

Ee learned thermodynamics you should

14:32

understand better yes that from something

14:35

hot to cold it means we

14:37

take heat yes that

14:40

means

14:41

we

14:43

take heat Okay so there is a

14:48

refrigerator yes a box like this yes the

14:51

equipment is quite

14:53

em yes quite sophisticated yes Ee with ee

14:57

refrigerant then ee with compressor

14:59

and so on yes then I have

15:01

food yes with tea temperature for example

15:05

then I want to make the food

15:07

to a lower temperature

15:10

which means I take heat from

15:12

ee the food I throw it out

15:15

or into the environment yes And if we

15:18

look here t t which is outside here

15:22

Suppose t outside from ee the refrigerator

15:25

or from the refrigerator is

15:27

higher right or

15:29

not I is higher Let's say yes

15:33

for example if in my house there is 25

15:35

degrees Celsius then I have

15:38

food which was ee 25 degrees

15:40

Celsius too then I can

15:43

lower it to around Let's say ee

15:45

a dozen yes maybe 12 to eh 15

15:49

degrees Celsius if in a

15:51

regular freezer, yes And if we look at it together

15:54

How can it violate the second law of

15:56

thermodynamics Is it true or not because

15:58

it should flow from a

16:00

higher temperature to a lower temperature,

16:01

yes And if we look here

16:04

Why is it possible that this refrigerator

16:07

has power, yes, surely He, ee,

16:10

if the refrigerator is functioning properly, yes,

16:13

he takes power from outside, yes

16:16

Therefore, later we will learn

16:18

together Why can a device

16:20

seem to violate the second law of thermodynamics,

16:23

yes, because it is possible if

16:25

there is power from outside, yes Well, this may be a

16:28

little story about

16:30

this application, later we will learn

16:32

more details about the refrigerator, yes

16:35

Then the second is the Pressure Cooker,

16:36

yes, this Pressure Cooker is a cooking tool

16:38

that can cook much

16:41

hotter, much faster than

16:43

the usual cooking method, yes, namely, we,

16:46

ee, we, ee, cover it with one, ee, a pan

16:51

or a pan that is under high pressure

16:54

so that the heat contained in the pan

16:56

will be much higher, yes,

16:58

then in terms of energy, yes,

17:00

power plants, ee,

17:03

fossil energy, there is Power PL, yes, fossil energy,

17:05

then even to the point of ee, studies from

17:09

power plants with energy

17:12

renewable in this case wind turbines yes

17:14

it is also an application of

17:16

thermodynamics yes then what we will

17:19

also discuss is about car engines yes

17:21

there are two strokes then there are four strokes yes

17:24

two strokes and four strokes later we

17:26

will see together yes Why is there

17:28

a fuel that when burned

17:31

then put in a mechanism

17:33

ee machining can make an object

17:37

move yes all are applications

17:39

of thermodynamics yes okay now

17:42

we discuss one or so many

17:44

vocabularies yes and terms in

17:46

Thermodynamics the first is called a

17:48

system the second is called the

17:51

environment yes and the third is

17:53

called the boundary yes so ee

17:56

this system is the quantity or material that

18:01

we study yes so that is what is called a

18:04

system yes So if I have

18:07

one object yes one object or I make

18:11

ee discontinuous Like this Well if

18:15

this one object I I I I Study yes

18:18

then I want to know ee its nature

18:20

I want to know its characteristics

18:22

then I want to know the

18:24

thermodynamic quantities yes then this is called a

18:27

system that we are ee

18:29

reviewing yes that is from ee the system

18:33

yes then what is outside the system yes

18:37

what is outside the system is the

18:39

environment yes so the environment is

18:42

an area that is in outside the system

18:45

or what is called

18:47

surroundings in English okay well

18:49

eh the boundary between the system and the

18:53

environment or real or

18:55

imaginary surface yes that is what is called a

18:57

boundary yes yes So

19:00

this dotted line is the boundary yes Well

19:03

then in simple analysis we

19:06

assume that the boundary

19:08

has zero thickness yes meaning it

19:11

has no thickness it also has no

19:13

mass and no volume yes to

19:15

make our analysis easier in

19:18

everyday life or in ee analysis which is

19:19

rnya Yes of course we have to take into account

19:22

from this boundary but in the

19:23

simple study of Thermodynamics which

19:26

we will discuss throughout this course

19:28

we assume that this boundary has no

19:31

mass has no thickness yes and

19:33

also has no volume Okay Well there is something

19:36

called a fixed boundary or

19:38

fixed and a moving boundary yes if the

19:41

boundary is fixed Yes we both know

19:43

that ee This is a boundary that does

19:47

not change yes for example I

19:49

have ee a box yes a cube yes ma'am

19:53

like this then I assume

19:55

as this is my system so this

19:58

is the

19:59

system then what is outside is the

20:02

environment yes then these boundaries are

20:04

fixed Yes meaning it is rigid yes a

20:07

rigid object yes which indeed

20:09

Ee cannot move yes Well this is a

20:12

fixed boundary or fixed yes but

20:15

boundaryy also or limit also it can

20:18

be a moving limit for

20:21

example piston yes so piston piston

20:24

cylinder Suppose like this yes

20:28

then He has

20:29

ee one

20:31

em is it possible in one form can

20:34

Elis shape can be round yes which can

20:37

move up and down yes when it goes down

20:40

yes then ee fluid pressure inside ee

20:44

piston increases volume

20:47

decreases yes And if it goes up yes if it goes up

20:50

then the pressure decreases and

20:53

the volume increases yes so the limit

20:56

can be a fixed limit and a

20:58

moving limit yes Well this is a

21:01

ee concept that must be mastered Okay

21:05

Well then there is something called a

21:08

closed system yes which is called

21:11

mass control well in

21:13

this system ee no mass

21:17

exchange is allowed yes mass exchange

21:20

between the system and the environment yes what is

21:22

allowed is energy exchange yes So

21:25

if he is ee Let's say

21:28

like this then I have ee

21:30

piston yes box like this yes this

21:33

is the limit for example then the right and

21:35

left are the limits yes then if this is ee

21:40

my system yes a system that has mass m yes

21:44

then outside this there is an

21:47

environment yes then the mass inside

21:51

mass control or inside

21:52

this closed system must not change whether

21:54

it decreases or increases yes So

21:58

no mass exchange is allowed

22:01

so Here I can write the

22:03

mass exchange, no, yes, or yes, there

22:08

should be no mass exchange, yes,

22:10

if it is in a closed system, yes, but

22:14

what is permitted is the exchange of

22:15

energy, yes, so here, if it is

22:18

an exchange of

22:21

energy, yes, this is

22:23

permitted, yes. For example, if

22:26

the environment has a lower temperature,

22:28

yes, like the coffee earlier, yes,

22:31

for example, 25 degrees Celsius, then the

22:33

closed system has a temperature of 80

22:36

degrees C. Celsius then of course there will be an

22:38

exchange of energy or energy transfer

22:40

from a higher temperature to a

22:42

lower temperature but the mass does not change

22:46

well it is different from an open system, yes Eh

22:49

if the open system is called a

22:51

control volume, yes So the volume does

22:53

not change, yes if it is

22:55

above the mass control, it means the mass

22:57

does not change, well in this system there can

23:00

be an exchange of mass and energy

23:02

between the system and the environment, yes For

23:05

example, a nozzle, yes Eh nozzle, eh nozzle,

23:10

like that nozzle,

23:12

like we want to water the plants, yes we

23:14

have a hose then we want to

23:16

accelerate the fluid, then we have to

23:18

reduce the surface of the hose, yes So more or

23:20

less the picture is

23:22

like this, yes from one surface, ee, yes

23:25

one surface that is

23:29

higher, yes then e here there is

23:33

a fluid that enters, yes with one

23:36

speed V1 then exits with a

23:38

speed V2, yes Where v2 is

23:41

greater than V1, yes eh

23:45

this green one is the limit, yes imaginary limit

23:52

Im iminer yes iminer iminer okay, well

23:59

then this is also an imaginary limit,

24:04

imaginary limit, yes so once again the limit

24:06

can be imaginary or indeed, eh one object

24:09

that is indeed limit Yes but anyway Eh

24:12

this is a control volume yes CV or

24:16

control volume yes So there is a

24:19

mass exchange because the fluid changes Is it true

24:21

or not yes there is water or gas coming in here

24:23

then there is also water or gas coming out

24:25

yes but what we see is that there is a volume

24:29

that does not change yes Therefore,

24:32

mass and

24:34

energy exchange between the system and the environment may occur yes

24:37

Well then there is one more system here

24:39

called an isolated system yes if the

24:42

system is isolated isolated system it is

24:45

not allowed to occur both yes

24:48

so mass exchange is not

24:51

allowed then

24:54

there is also no energy exchange yes this is an

24:57

isolated S

24:58

yes Well what is important is in

25:02

engineering analysis or analysis Yes we have to

25:04

define the system clearly

25:06

Is it open closed or

25:10

isolated yes Well with experience we

25:12

can see in ee applications of

25:14

thermodynamics When do we determine it

25:16

as a closed system When do we

25:18

determine it as an open system yes

25:21

And we have to know what mass exchange is

25:23

like and what energy exchange is also

25:25

like yes Next we will

25:28

discuss about properties yes properties or what

25:31

I usually call quantities yes Well

25:35

this property is a characteristic

25:37

of a system yes that is

25:40

the property yes Well

25:42

familiar properties for example there is pressure temperature

25:45

volume mass yes maybe I add

25:48

there is one more energy yes with the symbol e yes

25:52

Well that is eh example of a

25:56

property that is often we use it, yes,

25:59

this property is divided into two,

26:03

yes, so the quantity or here I call

26:06

it a property, yes, in thermodynamics,

26:09

there are two types, namely the quantity or

26:12

property I write here so that it is

26:14

not confused, intensive which does not

26:17

depend on mass, yes, and extensive which

26:19

depends on mass, yes, an example of intensive

26:23

is temperature, yes, So if intensive,

26:25

the easiest thing for us to know

26:27

which quantity is intensive or

26:30

extensive,

26:31

yes, so intensive does not depend on

26:37

mass, does not depend on

26:41

mass, yes, for example, if I have one

26:45

fluid or one liquid or one gas

26:47

that does have a temperature t, yes, it is easy

26:51

for us to know whether it is intensive or

26:52

extensive if I divide it in two, for example,

26:55

I divide the mass in

26:57

two, yes, I divide it in two, yes, there is a

27:01

first part, there is a second part, yes,

27:04

intensive does not depend on mass,

27:06

meaning the temperature is certainly the same, yes,

27:10

for example, if I have ee coffee

27:12

or tea, the temperature is 80, I divide it in two,

27:15

both are still 80, right? Is that right?

27:18

Both of them don't become 40, right? It would be

27:20

very strange if, for example, I have

27:22

one ee tea or coffee 80, I share it

27:25

with my friend, why is the temperature not divided in two?

27:28

Yes in our lives,

27:29

another example is pressure, if

27:31

I divide it by two, the pressure is the same, yes, and

27:34

also the density, yes, or in

27:37

Greek symbols, it is R. Well, while

27:40

extensive quantities are total mass and

27:43

total volume, yes, and of course, if

27:46

extensive, for example, I have v, it

27:48

is V like that, yes, E. Let's say

27:53

how much is 1 liter 2 l, yes, then I divide it by

27:56

two, of course, this becomes

27:58

1 V. This also becomes 12 V, yes, so that's the

28:02

difference between intensive and extensive, yes,

28:05

meanwhile, there is something called

28:07

extensive property, yes, which is per

28:10

unit mass, yes, which is called

28:12

specific volume or specific energy, yes,

28:16

so E is what is called a

28:19

specific quantity, yes, so specific volume

28:21

is the total volume per mass and

28:24

specific energy is the total energy per

28:26

mass, which is usually concluded

28:28

with a small e, this is concluded with a

28:31

small v, yes, later we will learn about

28:34

specific volume and then specific energy

28:36

too, eh, when we discuss

28:39

things related to

28:41

thermodynamics, yes, so that is a

28:43

property, yes, once again, there is something called a

28:46

system, there are systems that are open,

28:49

closed, and also isolated,

28:51

then we already know what a

28:53

property is, namely the characteristics of a

28:55

system, yes, as a constellation, it is actually the

28:58

same as humans, yes, humans

29:00

have characteristics. Yes,

29:02

the characteristics are like this, he is

29:03

like this, yes, it is more or less the same

29:05

as What are the properties of a

29:07

thermodynamic system, okay, let's continue,

29:11

yes, eh, there is something called a

29:13

state or in English it

29:15

is called a state, yes, so the state

29:18

or state of a

29:20

thermodynamic system is when

29:21

the system is in an unchanged condition, yes, it

29:24

means that in a certain state, yes, in

29:27

a certain state, the properties of a system

29:29

can be calculated or measured, yes,

29:32

and have a fixed or unchanged value,

29:35

yes, that is what is called a

29:37

state, yes, so for example, if I have,

29:41

once again, I have a box, yes, then

29:44

inside it there is a fluid, either gas

29:47

or e, Liquid, yes, then

29:51

when I measure the mass, 2 kg, then I

29:55

measure the

29:57

temperature, for example, 20 degrees Celsius,

30:01

then the volume, let's say 1 m³, yes,

30:04

so I can calculate everything,

30:07

yes, and it does not change, this is

30:11

called a state, yes, if I

30:15

heat it, yes, if I heat it, I

30:18

heat it, then of course there will be a

30:21

change, yes, if I heat it, there will be a change,

30:25

yes, for example, it will be

30:28

30 degrees Celsius, yes, the mass and eh,

30:32

the volume will also be modified, yes,

30:36

it will expands also if it is gas, yes,

30:38

the volume will be e, e, the bigger it is,

30:42

yes, what is interesting is that this is also a

30:44

state if it has indeed

30:46

eh, it has not changed, yes, like that, yes,

30:50

while there is something called a

30:52

state of equilibrium, yes, so there is a state or

30:55

condition that is called a state of

30:57

equilibrium or in English,

30:59

namely equilibrium state, yes, this is

31:02

a system that is said to be balanced,

31:04

so a system, a system is said to be

31:06

balanced if there is no potential that is

31:09

unbalanced, yes, so there is a keyword,

31:12

namely potential, yes, several

31:17

types of equilibrium that must be

31:20

balanced, yes, in a system,

31:22

if we want to say that it is in a

31:24

state of equilibrium, it is

31:26

thermal equilibrium, yes, thermal equilibrium, for

31:29

example, if I have, for example,

31:32

this box, yes, from 20, it rises to 30, right, well,

31:36

at that time,

31:39

eh, what happens

31:41

is, for example, I make it again, yes,

31:45

when it starts to be heated, yes, of course, not

31:48

everything immediately becomes 30, right,

31:50

because this area has started to be 30

31:53

degrees, yes, if there is fire below,

31:55

for example, there is fire below, yes, yes,

31:58

what is below, yes, then

31:59

above it, there is still 25, yes, over

32:01

here too maybe 20 yes still 20 eh

32:05

maybe not 20 yes maybe here 22

32:07

here 2 ee 24 yes here 23 and

32:11

so on yes Well this is said to be not yet in

32:13

thermal equilibrium so thermal equilibrium

32:15

is when everything has changed

32:18

yes for example I continue to increase

32:21

the heat until it reaches

32:22

equilibrium yes that means everything is

32:25

worth 30 degrees at every point of the

32:28

system that we are studying yes

32:32

then mechanical equilibrium yes when

32:35

there is no force ee or no pressure

32:39

yes which indeed ee yes does not change

32:42

the pressure yes so the pressure in

32:45

each of the areas here yes all of the

32:49

areas are all the same yes

32:51

So it is not in a state of ee changing or

32:54

in a state of non-equilibrium yes

32:56

then the phase yes the phase must also be weighed

32:58

then chemically it must also be in

33:00

equilibrium yes so the chemical composition

33:03

should not be ee in a state of change yes

33:06

so

33:08

for example if there is oxygen gas in here

33:11

Yes it is only oxygen gas

33:13

yes so it is in a state of equilibrium yes

33:16

like that okay Well next we

33:19

will discuss the state postulate yes

33:22

Well the state postulate ee so if we

33:26

maybe before I discuss the

33:28

definition of the state postulate yes if I

33:30

have a system like this yes I

33:34

have a system and I want to know its

33:38

characteristics or properties

33:40

for example there is P I want to know its v

33:43

I want to know its t I want to know

33:45

its energy and so on yes then ee Do

33:49

I have to know all yes that's

33:51

the question yes Can I or not

33:54

I only know ee P and I only know

33:58

its t Then I can derive

34:00

the others yes Well it turns out it can yes only

34:03

the question is how much is the minimum quantity

34:05

that we have to know to derive the

34:09

other quantities so that is the

34:11

basis of thinking of the state postulate yes

34:14

because in a system there are

34:16

many characteristics but how much is the

34:18

minimum quantity that I have to

34:20

know to derive the

34:22

other quantities yes so the state postulate is the

34:25

state of a compressed system here there

34:27

is

34:28

a keyword yes that is compressed

34:30

meaning there are no forces yes

34:33

other forces such as e force yes what is the

34:36

fluid like is moving then there is an

34:38

electric force there is a magnetic force that does

34:40

cause imbalance that is

34:42

the definition of a compressed system yes it

34:45

can be described the state of the system

34:47

yes by two

34:51

mutually independent intensive properties so remember

34:53

intensive is a quantity that if I

34:55

divide the volume does not change which is mutually

34:59

independent Yes that is the requirement for eh

35:02

to obtain the state of

35:04

eh these two quantities they must be intensive

35:07

and mutually independent yes Well two

35:09

properties can be said to be independent if

35:11

one of the properties is changed the other

35:13

is kept constant yes that is an example

35:18

I want to know the

35:19

e property or quantity of a

35:22

system yes we know there is P there is V there is

35:25

t e and so on yes well I only

35:28

know two but the condition is that both

35:31

must be intensive and independent for

35:33

example P and t are both

35:38

intensive yes and

35:43

extensive Okay intensive and extensive

35:47

so I can increase the t so the

35:51

t is increased while

35:54

maintaining the value of p yes that is

35:57

the definition of independent so they do not

35:59

affect each other directly yes

36:01

like that yes For example if I

36:03

know P and t then I can decrease the

36:07

p yes or the volume by means of yes the

36:10

formula that we may have studied

36:12

together in high school namely yes the Boile G

36:14

lusak formula yes Where pv / t

36:18

= constant yes so that is the condition to

36:21

obtain the

36:22

ee magnitude of a state or

36:25

property of a state it must be

36:28

At least we must know two properties

36:30

that are intensive and independent yes that

36:34

is an example of ee from this yes Well

36:37

another example is P and specific

36:40

volume right volume yes so P

36:44

pressure pressure eh sorry It should not be P

36:49

and V yes they influence each other yes

36:50

So if P and V are not mutually

36:53

independent yes but the

36:55

other independent ones are ee these are not

36:57

mutually independent yes I forgot earlier they are not

36:59

mutually

37:02

independent yes why yes If I

37:05

increase p the v will also change yes

37:07

Well I mean additional examples

37:10

for intensive and independent ones

37:14

are t and speciesfic volume yes this is the

37:17

same yes I increase the t the

37:20

volume can still be maintained yes yes

37:23

For example I have a vessel yes

37:25

box or cylinder I heat it yes

37:29

but I keep the volume

37:33

unchanged so if it is Gas of course

37:35

it will start to heat yes but I can

37:37

keep the volume constant yes Until

37:40

a certain level of course before yes the limit

37:42

is damaged yes like that Well that

37:45

is the postulate of the state Okay Well

37:48

next there is something called a

37:50

process and cycle yes process and cycle

37:55

so this process is a change of a

37:57

system from an equilibrium state to

37:59

another equilibrium state for example yes Ee

38:03

if I have I will draw it first yes

38:06

I have two properties in ee one

38:10

or in the XY axis yes for example

38:14

this property 1 this property

38:19

du yes usually this property ee

38:23

volume This property of pressure yes ee

38:26

or vice versa yes yes can p can V yes

38:31

can p t yes and and and so on yes

38:34

Well ee if I draw it here yes

38:38

He has for example

38:40

P1 P1 then here there is P2 P2 yes

38:46

then he

38:48

ee processes Yes like this Well for example

38:53

curved yes then he can be straight

38:55

like this the change can be like this

38:58

yes There are many paths yes later we will

39:00

learn together it turns out that different paths

39:03

or what is called pet or

39:05

path Yes it can cause differences in the

39:08

characteristics of the system In this case

39:10

the work produced yes Well that will be

39:12

discussed later in the lecture or video

39:14

Next yes like that yes So this

39:17

is a state of equilibrium one this is

39:20

state 1 then it changes to

39:23

state

39:24

two yes like that yes So this is an example

39:28

yes so ee it is called a

39:32

process yes and a series of states Why is it

39:34

called a series of states because if

39:37

he is in the middle path Here he passes through

39:39

every equilibrium point Is that right or not

39:41

yes he passes through every ee

39:45

equilibrium point here The small ones yes

39:47

so that is a series of states that are

39:49

passed throughout the process namely path yes

39:51

this can be called path one path two

39:53

path 3 each of which passes through

39:56

processes or sor

39:58

small states like that Well then

40:02

there is one process that will be the assumption

40:05

of our discussion in thermodynamics,

40:08

namely the quasi-static process, yes Well this

40:10

needs understanding if it's your

40:13

first time hearing this, so the

40:15

quasi-static or quasi-balance process

40:17

is a very

40:19

slow process where the system can change

40:22

internally so that all

40:24

parts of the process in the system

40:27

change simultaneously, yes For example,

40:30

if I have a piston, let's say

40:32

the piston is facing to the right now, yes, it's a

40:34

little different, yes, here there is a limit that

40:38

can move,

40:40

yes, then I press it, yes, so when

40:44

I press the particle at the end

40:46

here, it will press, yes, the particle

40:49

here, maybe it will also

40:50

press there, yes, then the value of P, yes,

40:55

or the momentum of this particle, yes, or the

40:57

right of the wall here, yes,

40:59

between the particle and the wall, yes,

41:03

they change slowly, yes,

41:07

meaning the p changes, yes, then

41:11

each of the particles also

41:12

adjusts, yes,

41:15

so the process is slow,

41:17

not fast, so the p changes,

41:20

then the volume changes and they do

41:22

not overtake each other, yes, so that's the

41:24

difference between a fast process

41:27

or a fast process quasistatic yes so

41:31

every property that changes does not

41:34

precede each other so One of the

41:36

properties changes yes internally

41:38

the system adjusts to the

41:40

other properties yes For example I

41:43

enlarge this image yes if this is

41:47

from this one state to the

41:50

second state yes then there is a process

41:53

Let's say straight yes so it's easy

41:56

this is the process yes Well Is

41:59

n't in every process This

42:01

direction is probably here yes Isn't in

42:03

every process we have

42:07

small states yes Let

42:10

's say state 1A 1B and so on yes Well in

42:13

every state of course

42:16

it

42:17

has properties too it has P P and

42:21

t also here is also the same it has P

42:24

P and t also yes well every Quantity

42:28

changes yes for example yes this p p accent this

42:32

P accent accent accent Dou accent Dou accent

42:35

yes it changes yes but they do not precede each other

42:39

yes Nothing is faster

42:41

than the other yes So when

42:43

the pressure changes the volume also

42:45

changes the t also t also

42:49

changes yes Well this process is an

42:51

assumptive process yes or assumption yes

42:55

which in real life eh

42:58

we don't encounter much but in terms of

43:00

eh static brush process that is in

43:02

thermodynamics we use the

43:04

assumptions, yes, for what to calculate

43:07

maximum efficiency, we will

43:09

learn later in the next chapters, yes,

43:11

for example, some types of processes that

43:13

we may have learned

43:15

in high school, there is something called

43:16

isothermal, namely constant t, isohoric, namely

43:20

constant v, yes, there is something

43:23

called isobaric or

43:26

constant p, yes, or adiabatic, yes, So there

43:30

is no exchange or no change

43:32

in heat, yes, So there is no heat

43:35

flowing, yes, like that, yes, so it

43:39

is an isothermal, isohoric,

43:40

isobaric and

43:42

adiabatic process, yes, okay, yes, like that, yes, then

43:46

this is what we will probably

43:49

learn throughout this course, yes,

43:52

then what is related to the

43:55

process is a cycle, yes, a cycle

43:58

is a system that goes

44:01

through a series of

44:04

processes, yes, whose condition returns to its

44:07

original state, yes, So if I make it

44:10

again here, the

44:14

x-axis is usually P, the y-axis is

44:19

usually P, yes, Uh, pressure and

44:22

volume, yes, for example, the first state,

44:27

then it moves to the second state, then it moves

44:29

to the third state, yes,

44:31

then it moves again, back

44:34

to the state that was first Yes, this is

44:36

called a cycle, yes, this is the

44:38

first process, then it tilts a little bit, the

44:41

second process, yes, then it comes back

44:43

here, up Sorry, we're back

44:46

to it, I'll make a new line, yes,

44:50

like this, yes, So this is what is called a

44:52

cycle, ee, cycle, cycle, yes, so one, second, two, third,

44:58

three,

45:03

back to one, yes, this is called a

45:05

cycle, yes, later we will

45:06

also learn a lot of thermodynamic cycles,

45:09

yes, which are indeed the characteristics of

45:12

several applications or engines that

45:16

we will learn, such as the

45:18

steam engine cycle, then the ee, ee,

45:22

refrigeration cycle, yes, those are examples of

45:24

cycles that we will learn

45:26

later, okay, now, ee, this is the

45:29

last part, namely the zeroth law of

45:32

thermodynamics, yes, so the Zeroth Law of

45:34

Thermodynamics is interesting, yes, why is

45:38

there a zeroth law? Yes, because there is the

45:41

first law, then there is the second law that

45:43

we discussed in the

45:46

previous slide, yes, why is there a

45:49

zeroth law, it turns out that this zeroth law was

45:50

discovered, maybe not discovered, yes,

45:53

formulated by scientists, yes,

45:57

long after the first law and the

45:59

second law, yes, so

46:01

ee, so far, yes, even em, because

46:06

far away, yes, it's been 50 years, yes,

46:09

So almost half a century, the first law

46:11

already exists, the second law already exists, eh,

46:13

it turns out there is a zeroth law which is

46:15

considered much more fundamental

46:16

than law 1 and law 2, that's why it's

46:18

called the zeroth law Yes, like

46:21

that Well, this zeroth law speaks or

46:24

has a definition or has a formulation, ee

46:26

ee, so if there are two objects that are in

46:30

thermal equilibrium with a third object,

46:32

then the two objects are in

46:34

thermal equilibrium, yes, for example, ee, if I

46:37

have one object, for example, a box

46:42

like this, then I have another object, yes,

46:50

Okay, I have another one, for example, this B,

46:54

this B,

46:57

yes, then this one is a, yes,

47:00

then a and b are in equilibrium with

47:02

object C, yes, weigh it with object C, yes,

47:06

I make

47:10

another box, yes, more or less like this, yes, this

47:13

is C, yes, So if

47:17

a If A and C are in

47:22

thermal equilibrium, it means the temperature is the same, right,

47:25

then B and C are in thermal equilibrium

47:34

too, yes,

47:36

then a and b are in

47:40

thermal equilibrium Well, maybe you think up to

47:42

here, yes, Oh yes, ten That's all If A

47:44

and C are the same temperature or

47:47

thermal equilibrium B and C are thermal equilibrium well

47:49

obviously A and thermal equilibrium base Well

47:51

why should it be formulated Well that's the

47:53

importance there is one ee law yes there is

47:57

one phenomenon that is more

47:59

fundamental yes which indeed It

48:00

seems natural yes

48:02

but they call it the

48:04

people call it the law of Keol

48:06

yes Well the concept of temperature is actually

48:10

related to the law of Keol yes

48:12

in its application the concept of temperature or

48:14

temperature measuring instrument is two objects

48:17

in a state of thermal equilibrium if

48:19

both objects have the

48:21

same temperature yes maybe you also think

48:23

here yes yes yes yes yes if I have

48:25

two objects eh thermal equilibrium both

48:29

have the same temperature yes but that

48:30

is the first way of thinking that

48:32

humans can measure temperature

48:35

using one tool yes So if I

48:37

have one ee object yes then I

48:40

dip the thermometer yes then

48:43

this thermometer will start measuring yes with

48:46

its scale t for example in degrees

48:49

Celsius yes then I can know

48:52

the temperature of eh this substance yes or

48:55

system

48:57

by looking at the temperature of the

48:59

thermometer yes And they are made or yes

49:03

Legally Oh this thermodynamics ee the

49:06

thermometer has the

49:08

same temperature as the system yes

49:09

Therefore the temperature measurement that

49:11

we have been doing is

49:15

one of the applications of ee the Zeroth Law of

49:18

Thermodynamics yes yes even though this

49:20

looks ee simple yes but it must be

49:23

understood that ee this is

49:26

one of the ee laws that is indeed important Yes

49:28

because it is so important ee was discovered long

49:31

after law 1 and law 2 so it

49:32

is called the zeroth law of thermodynamics yes

49:36

okay that's all for today's lecture ee

49:38

in this video I mean and EE

49:41

Hopefully all my friends or anyone

49:43

who watches this video can also

49:45

understand the basic concepts of vocabulary and also

49:48

many terms in thermodynamics Okay see

49:50

you in lecture or in the next video

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