Termodinamika Kuliah 1 - Pendahuluan dan Konsep Dasar
Hello, welcome to the
thermodynamics course and this is the
first lecture which is about the introduction and
basic concepts So there are five contents that
we will discuss in this video in
this first lecture, the first we will
discuss the definition of thermodynamics and
its relationship to energy Then the
second we will discuss the system and
control volume, the third we will
discuss the properties of state and
equilibrium, the fourth we will
discuss what is the process and cycle, the
fifth we will discuss the zeroth law of
thermodynamics so in
this first lecture we will discuss more
Emm terms and also vocabulary that
we will use throughout the
thermodynamics lecture, yes Well here there is
one example in the picture on
the right, this is an example of the
application of thermodynamics, namely
Power
Plan or power plant, yes, so
thermodynamics is a
science that is actually very close
to our lives, so we will
discuss some important vocabulary and terms,
yes In this first lecture
Well, we will discuss from the term, yes,
or from the name of thermodynamics,
so thermodynamics can be
defined as the science of energy
So if statistics is the science
of data, yes, while thermodynamics
is the science of energy In essence we
discuss all forms of ee
energy changes, yes, it is a study
of thermodynamics, well, then from the
root of the word thermodynamics comes from
Greek, namely terme which
means heat or color and dynamic yes
or dynamis yes which means power, so
e thermodynamics is actually from the beginning of
e the development of human civilization, it is
a science that discusses the
conversion of heat
into power or work into power or
work, yes, One of the discoveries or
one of the tools that ee the first time
thermodynamics was used, it seems, is
ee the steam engine, yes, it converts heat
into power or work, which is
one of the markers of the
industrial revolution, well, what we will discuss throughout
eh the thermodynamics course
are the laws that are indeed the laws
of Thermodynamics, the
first is the first law, yes, the
first law of thermodynamics, this is
none other than the law of conservation of energy,
yes, and energy is a quantity or
property of thermodynamics, yes, And we
have studied together even in elementary school, yes, elementary school, junior high school,
high school about the law of
conservation of energy, yes, so if ee there is
one object above ee one height H,
yes, then he has
ee potential energy yes that is mgh yes
then he will change ee
this potential energy when the object
falls into kinetic energy yes 1/2 MV
p^ Well that is more or less the law of
conservation of energy yes in ee mechanics
Well here we will also discuss later the
first law of thermodynamics in
relation to the law of conservation of energy, namely the
relationship between work then there is heat
then there is internal energy yes
we have actually studied all of them in high school
but in thermodynamics in this lecture in
engineering we will deepen
from ee the law of conservation of energy
yes Well the first law of thermodynamics
deals more with the titas yes quantity quantity
while eh for
this second law discusses more about the quality of
energy Well this may be something that is still foreign to
our ears maybe yes when we
first studied thermodynamics e
in engineering or on campus or at
university yes that we will discuss the
quality of energy and not just
quantity yes so the second law of
thermodynamics will be related to
entropy yes E where the second law of
dynamics states that energy
not only has quantity but
also quality and the conditions for a process to
occur are that it takes place in a direction where
the quality decreases yes So it does not
increase so naturally ee energy
will flow from
higher quality to lower quality energy
yes For example, there is
one picture on the right side of
this slide yes there is one or a cup of
coffee yes if this is coffee
that may have just been served yes in a
cafe Let's say He has a temperature of 70
degrees Celsius yes Well 70 degrees
Celsius we can interpret this as
temperature yes if we put the temperature
there thermometer there we put the
temperature sensor yes it reads 70 degrees
Celsius yes Well this is one ee
quantity later yes quantity or
property we will study later namely ee
temperature but here of course there are
many ee water molecules yes water molecules
then there are many particles that
move and
EE this collective movement
causes the coffee to be hot yes Well
in this coffee there is energy yes Well
there is energy that will move to the
environment yes so if this cafe
Let's say it has air conditioning He has a temperature of 18
to 20 degrees Celsius then
the coffee itself is 70 degrees Celsius and
in our daily lives we
know that there will be a flow of heat yes
Q with the symbol q yes E there is a flow of
heat from this coffee to the environment in
this case is yes cafe So
if the first law of thermodynamics
states that in this coffee
there is energy, namely the quantity, the
second law of thermodynamics states
that there will be a flow of energy from
higher quality energy, namely
in this case coffee, yes, because its quality is
higher. It has a
higher quality and value ee compared
to the environment, yes, so there
will be a flow of heat, yes, from the
EE temperature is higher to the temperature is
lower or the quality is
higher to the quality is lower, yes,
why is it called a
higher quality, yes, because with
this 70 degrees Celsius heat, if we
convert it into work later with the
symbol W, yes, maybe it should be white
with the symbol w B, yes, then the work of 70
degrees Celsius will be much
greater than the 18 to 20
degrees Celsius, yes, and that is nothing other than
the principle of
thermodynamics itself, yes, namely converting
heat into power or work, the
higher the heat, the greater
or better we can
convert it into ee power or work, yes,
Well, the second law of thermodynamics states
that there will be a flow of heat and from
or there will be a flow of energy from the
higher quality to the
lower and Not on the contrary, yes,
for example,
Ee, we cannot heat this coffee to
70 degrees Celsius by taking
heat from outside. Is that right or not?
If, for example, Ee, we might
do it, then it is a violation, yes, if
someone says that, Okay, if I
have coffee at 70 degrees Celsius in
the environment or in a room that is 18
to 20 degrees Celsius, then I can
make
this temperature lower, let's say it
becomes 15 degrees Celsius, then
this 70 degrees Celsius rises, let's
say it becomes 75 degrees Celsius.
Well, this is a process that is
impossible in our
daily lives. Well, this process can be
done if we
add work from outside. Well, that is the
ee principles that
we will learn throughout
this course, yes, this is an
everyday example, but from this everyday example,
we can know that thermodynamics
is in our daily lives,
which we sometimes take for granted. Well,
hopefully after studying this, we will
no longer take it for granted, we will start
to think more deeply,
so we can study every
phenomenon that is around us and
can use it for applications in
our lives. Okay, let's continue the
study of thermodynamics. it is divided
into two, namely classical thermodynamics
which will be the discussion of
this course, yes, or in this video or in this
series of videos, yes, so
this course, yes, or this series of videos, if
you are not my students
who are ee enrolled or registered at
Unpar, yes, throughout the playlist of
this course, we will discuss only
classical thermodynamics, yes,
this classical thermodynamics is a
thermodynamic approach that does not
need to take into account the behavior of the
constituent particles, yes, So you could say that
this classical thermodynamics is a much
more
macroscopic study, yes, macroscopic, yes, for example,
we will calculate or yes, measure Yes,
if in the practicum in thermodynamics,
we will make measurements or
we calculate P, yes, which is
pressure, then there is another quantity, ee,
namely
volume, yes, then there is another one, namely
temperature, now this is the most frequent
quantity that we will calculate ee
in thermodynamics, yes, what is interesting
is There is a second study, namely
classical or statistical thermodynamics Oh,
sor, namely statistical thermodynamics, yes,
this second study,
statistical thermodynamics, is a
thermodynamic approach that takes into account the
average properties of the constituent particles, so It
can be said that
statistical thermodynamics is a
more microscopic study, yes. For example,
if in classical terminodynamics it
discusses pressure, yes, then in
statistical thermodynamics, yes, it discusses
pressure in the form of collisions between
particles, so let's say I have a
piston or a vessel, yes,
then I press it, yes, or
just a piston, yes, I press it, yes, here there is
a part that can press the
fluid, yes, then inside
here there is the fluid, yes, and in
the fluid, the liquid or gas, so this
can be a liquid or gas,
yes, the liquid and gas certainly
consist of atoms and molecules, right or
not, yes, Therefore, I give
an illustration here, yes, there are molecules
and atoms that EE, let's say it is a
gas or liquid, yes, and in
statistical thermodynamics, if we look at it in a
much more microscopic form of pressure,
yes, so if we press it, of course there
will be an increase in pressure, yes,
because I press it, I compress
it, yes, so the pressure increases, yes, the pressure increases,
the volume decreases, yes, and that is
a relation that we often use
in everyday life, so
the pressure increases, then the volume
will decrease, yes, And if I only
measure or calculate the pressure, then
I studying thermodynamics
classically but if I look at
each ee particle of course the
particle will move and will
start to press yes parts of
the wall right so if I
zoom in there is one molecule that starts to
press to the right ee Sori down
then there is a molecule that presses to
the right yes to the right wall then
there is a molecule that also presses up
because it starts to be pressed by part of the
piston then I calculate the
average here I calculate the average
of the collisions yes so the
average of the
collisions yes or ee momentum yes momentum
of the collisions yes Well this is what
will collectively
determine the pressure that we
calculate Okay so once again the
classical thermodynamics that we will
discuss throughout this course or
throughout this video playlist is
the macroscopic one yes which is the
result of the motion of the constituent particles
without having to take into account the
behavior of the particles so
we just calculate the p yes the pressure
or we just measure in experiments
for example without having to know that there are
how many particles EE
have collisions so much then
how many particles have e
momentum so much yes sor not collisions
should be momentum, yes, how much is it, right?
Well, while classical thermodynamics, yes,
we can make a graph here,
for example, there are a number of e particles,
here it should be, for example, momentum, yes, Ee
momentum, momentum p-nya P ee, meaning p
p momentum, yes, m * v, yes, then on the
y-axis there is the number of particles, yes,
of course it is not uniform, there are those with large e
momentum, then maybe
ee is in the middle of the value, then
there are also smaller ones, they are
higher, yes, this is eh, each
particle that we actually calculate
statistically How many particles
have a certain momentum, how
many particles have a
certain momentum, yes, then we take the
average and it turns out that this is actually
one entity or one quantity or one
property, later we will study it which is
called pressure, yes, so
our study is classical thermodynamics, yes,
hopefully this example can help What is the
difference between classical and statistical, okay, well,
next, we will probably
study together Later in
this course, there are applications of
thermodynamics, yes, and in
everyday life, we see this application,
the first is a refrigerator, yes,
this refrigerator, ee, transfers
heat, yes, transfers heat from the inside,
so transfers heat from inside yes
because if I have a drink that is EE
in room temperature or food in
room temperature I want to make it
cold yes and that means from hot
to cold yes now if you have
Ee learned thermodynamics you should
understand better yes that from something
hot to cold it means we
take heat yes that
means
we
take heat Okay so there is a
refrigerator yes a box like this yes the
equipment is quite
em yes quite sophisticated yes Ee with ee
refrigerant then ee with compressor
and so on yes then I have
food yes with tea temperature for example
then I want to make the food
to a lower temperature
which means I take heat from
ee the food I throw it out
or into the environment yes And if we
look here t t which is outside here
Suppose t outside from ee the refrigerator
or from the refrigerator is
higher right or
not I is higher Let's say yes
for example if in my house there is 25
degrees Celsius then I have
food which was ee 25 degrees
Celsius too then I can
lower it to around Let's say ee
a dozen yes maybe 12 to eh 15
degrees Celsius if in a
regular freezer, yes And if we look at it together
How can it violate the second law of
thermodynamics Is it true or not because
it should flow from a
higher temperature to a lower temperature,
yes And if we look here
Why is it possible that this refrigerator
has power, yes, surely He, ee,
if the refrigerator is functioning properly, yes,
he takes power from outside, yes
Therefore, later we will learn
together Why can a device
seem to violate the second law of thermodynamics,
yes, because it is possible if
there is power from outside, yes Well, this may be a
little story about
this application, later we will learn
more details about the refrigerator, yes
Then the second is the Pressure Cooker,
yes, this Pressure Cooker is a cooking tool
that can cook much
hotter, much faster than
the usual cooking method, yes, namely, we,
ee, we, ee, cover it with one, ee, a pan
or a pan that is under high pressure
so that the heat contained in the pan
will be much higher, yes,
then in terms of energy, yes,
power plants, ee,
fossil energy, there is Power PL, yes, fossil energy,
then even to the point of ee, studies from
power plants with energy
renewable in this case wind turbines yes
it is also an application of
thermodynamics yes then what we will
also discuss is about car engines yes
there are two strokes then there are four strokes yes
two strokes and four strokes later we
will see together yes Why is there
a fuel that when burned
then put in a mechanism
ee machining can make an object
move yes all are applications
of thermodynamics yes okay now
we discuss one or so many
vocabularies yes and terms in
Thermodynamics the first is called a
system the second is called the
environment yes and the third is
called the boundary yes so ee
this system is the quantity or material that
we study yes so that is what is called a
system yes So if I have
one object yes one object or I make
ee discontinuous Like this Well if
this one object I I I I Study yes
then I want to know ee its nature
I want to know its characteristics
then I want to know the
thermodynamic quantities yes then this is called a
system that we are ee
reviewing yes that is from ee the system
yes then what is outside the system yes
what is outside the system is the
environment yes so the environment is
an area that is in outside the system
or what is called
surroundings in English okay well
eh the boundary between the system and the
environment or real or
imaginary surface yes that is what is called a
boundary yes yes So
this dotted line is the boundary yes Well
then in simple analysis we
assume that the boundary
has zero thickness yes meaning it
has no thickness it also has no
mass and no volume yes to
make our analysis easier in
everyday life or in ee analysis which is
rnya Yes of course we have to take into account
from this boundary but in the
simple study of Thermodynamics which
we will discuss throughout this course
we assume that this boundary has no
mass has no thickness yes and
also has no volume Okay Well there is something
called a fixed boundary or
fixed and a moving boundary yes if the
boundary is fixed Yes we both know
that ee This is a boundary that does
not change yes for example I
have ee a box yes a cube yes ma'am
like this then I assume
as this is my system so this
is the
system then what is outside is the
environment yes then these boundaries are
fixed Yes meaning it is rigid yes a
rigid object yes which indeed
Ee cannot move yes Well this is a
fixed boundary or fixed yes but
boundaryy also or limit also it can
be a moving limit for
example piston yes so piston piston
cylinder Suppose like this yes
then He has
ee one
em is it possible in one form can
Elis shape can be round yes which can
move up and down yes when it goes down
yes then ee fluid pressure inside ee
piston increases volume
decreases yes And if it goes up yes if it goes up
then the pressure decreases and
the volume increases yes so the limit
can be a fixed limit and a
moving limit yes Well this is a
ee concept that must be mastered Okay
Well then there is something called a
closed system yes which is called
mass control well in
this system ee no mass
exchange is allowed yes mass exchange
between the system and the environment yes what is
allowed is energy exchange yes So
if he is ee Let's say
like this then I have ee
piston yes box like this yes this
is the limit for example then the right and
left are the limits yes then if this is ee
my system yes a system that has mass m yes
then outside this there is an
environment yes then the mass inside
mass control or inside
this closed system must not change whether
it decreases or increases yes So
no mass exchange is allowed
so Here I can write the
mass exchange, no, yes, or yes, there
should be no mass exchange, yes,
if it is in a closed system, yes, but
what is permitted is the exchange of
energy, yes, so here, if it is
an exchange of
energy, yes, this is
permitted, yes. For example, if
the environment has a lower temperature,
yes, like the coffee earlier, yes,
for example, 25 degrees Celsius, then the
closed system has a temperature of 80
degrees C. Celsius then of course there will be an
exchange of energy or energy transfer
from a higher temperature to a
lower temperature but the mass does not change
well it is different from an open system, yes Eh
if the open system is called a
control volume, yes So the volume does
not change, yes if it is
above the mass control, it means the mass
does not change, well in this system there can
be an exchange of mass and energy
between the system and the environment, yes For
example, a nozzle, yes Eh nozzle, eh nozzle,
like that nozzle,
like we want to water the plants, yes we
have a hose then we want to
accelerate the fluid, then we have to
reduce the surface of the hose, yes So more or
less the picture is
like this, yes from one surface, ee, yes
one surface that is
higher, yes then e here there is
a fluid that enters, yes with one
speed V1 then exits with a
speed V2, yes Where v2 is
greater than V1, yes eh
this green one is the limit, yes imaginary limit
Im iminer yes iminer iminer okay, well
then this is also an imaginary limit,
imaginary limit, yes so once again the limit
can be imaginary or indeed, eh one object
that is indeed limit Yes but anyway Eh
this is a control volume yes CV or
control volume yes So there is a
mass exchange because the fluid changes Is it true
or not yes there is water or gas coming in here
then there is also water or gas coming out
yes but what we see is that there is a volume
that does not change yes Therefore,
mass and
energy exchange between the system and the environment may occur yes
Well then there is one more system here
called an isolated system yes if the
system is isolated isolated system it is
not allowed to occur both yes
so mass exchange is not
allowed then
there is also no energy exchange yes this is an
isolated S
yes Well what is important is in
engineering analysis or analysis Yes we have to
define the system clearly
Is it open closed or
isolated yes Well with experience we
can see in ee applications of
thermodynamics When do we determine it
as a closed system When do we
determine it as an open system yes
And we have to know what mass exchange is
like and what energy exchange is also
like yes Next we will
discuss about properties yes properties or what
I usually call quantities yes Well
this property is a characteristic
of a system yes that is
the property yes Well
familiar properties for example there is pressure temperature
volume mass yes maybe I add
there is one more energy yes with the symbol e yes
Well that is eh example of a
property that is often we use it, yes,
this property is divided into two,
yes, so the quantity or here I call
it a property, yes, in thermodynamics,
there are two types, namely the quantity or
property I write here so that it is
not confused, intensive which does not
depend on mass, yes, and extensive which
depends on mass, yes, an example of intensive
is temperature, yes, So if intensive,
the easiest thing for us to know
which quantity is intensive or
extensive,
yes, so intensive does not depend on
mass, does not depend on
mass, yes, for example, if I have one
fluid or one liquid or one gas
that does have a temperature t, yes, it is easy
for us to know whether it is intensive or
extensive if I divide it in two, for example,
I divide the mass in
two, yes, I divide it in two, yes, there is a
first part, there is a second part, yes,
intensive does not depend on mass,
meaning the temperature is certainly the same, yes,
for example, if I have ee coffee
or tea, the temperature is 80, I divide it in two,
both are still 80, right? Is that right?
Both of them don't become 40, right? It would be
very strange if, for example, I have
one ee tea or coffee 80, I share it
with my friend, why is the temperature not divided in two?
Yes in our lives,
another example is pressure, if
I divide it by two, the pressure is the same, yes, and
also the density, yes, or in
Greek symbols, it is R. Well, while
extensive quantities are total mass and
total volume, yes, and of course, if
extensive, for example, I have v, it
is V like that, yes, E. Let's say
how much is 1 liter 2 l, yes, then I divide it by
two, of course, this becomes
1 V. This also becomes 12 V, yes, so that's the
difference between intensive and extensive, yes,
meanwhile, there is something called
extensive property, yes, which is per
unit mass, yes, which is called
specific volume or specific energy, yes,
so E is what is called a
specific quantity, yes, so specific volume
is the total volume per mass and
specific energy is the total energy per
mass, which is usually concluded
with a small e, this is concluded with a
small v, yes, later we will learn about
specific volume and then specific energy
too, eh, when we discuss
things related to
thermodynamics, yes, so that is a
property, yes, once again, there is something called a
system, there are systems that are open,
closed, and also isolated,
then we already know what a
property is, namely the characteristics of a
system, yes, as a constellation, it is actually the
same as humans, yes, humans
have characteristics. Yes,
the characteristics are like this, he is
like this, yes, it is more or less the same
as What are the properties of a
thermodynamic system, okay, let's continue,
yes, eh, there is something called a
state or in English it
is called a state, yes, so the state
or state of a
thermodynamic system is when
the system is in an unchanged condition, yes, it
means that in a certain state, yes, in
a certain state, the properties of a system
can be calculated or measured, yes,
and have a fixed or unchanged value,
yes, that is what is called a
state, yes, so for example, if I have,
once again, I have a box, yes, then
inside it there is a fluid, either gas
or e, Liquid, yes, then
when I measure the mass, 2 kg, then I
measure the
temperature, for example, 20 degrees Celsius,
then the volume, let's say 1 m³, yes,
so I can calculate everything,
yes, and it does not change, this is
called a state, yes, if I
heat it, yes, if I heat it, I
heat it, then of course there will be a
change, yes, if I heat it, there will be a change,
yes, for example, it will be
30 degrees Celsius, yes, the mass and eh,
the volume will also be modified, yes,
it will expands also if it is gas, yes,
the volume will be e, e, the bigger it is,
yes, what is interesting is that this is also a
state if it has indeed
eh, it has not changed, yes, like that, yes,
while there is something called a
state of equilibrium, yes, so there is a state or
condition that is called a state of
equilibrium or in English,
namely equilibrium state, yes, this is
a system that is said to be balanced,
so a system, a system is said to be
balanced if there is no potential that is
unbalanced, yes, so there is a keyword,
namely potential, yes, several
types of equilibrium that must be
balanced, yes, in a system,
if we want to say that it is in a
state of equilibrium, it is
thermal equilibrium, yes, thermal equilibrium, for
example, if I have, for example,
this box, yes, from 20, it rises to 30, right, well,
at that time,
eh, what happens
is, for example, I make it again, yes,
when it starts to be heated, yes, of course, not
everything immediately becomes 30, right,
because this area has started to be 30
degrees, yes, if there is fire below,
for example, there is fire below, yes, yes,
what is below, yes, then
above it, there is still 25, yes, over
here too maybe 20 yes still 20 eh
maybe not 20 yes maybe here 22
here 2 ee 24 yes here 23 and
so on yes Well this is said to be not yet in
thermal equilibrium so thermal equilibrium
is when everything has changed
yes for example I continue to increase
the heat until it reaches
equilibrium yes that means everything is
worth 30 degrees at every point of the
system that we are studying yes
then mechanical equilibrium yes when
there is no force ee or no pressure
yes which indeed ee yes does not change
the pressure yes so the pressure in
each of the areas here yes all of the
areas are all the same yes
So it is not in a state of ee changing or
in a state of non-equilibrium yes
then the phase yes the phase must also be weighed
then chemically it must also be in
equilibrium yes so the chemical composition
should not be ee in a state of change yes
so
for example if there is oxygen gas in here
Yes it is only oxygen gas
yes so it is in a state of equilibrium yes
like that okay Well next we
will discuss the state postulate yes
Well the state postulate ee so if we
maybe before I discuss the
definition of the state postulate yes if I
have a system like this yes I
have a system and I want to know its
characteristics or properties
for example there is P I want to know its v
I want to know its t I want to know
its energy and so on yes then ee Do
I have to know all yes that's
the question yes Can I or not
I only know ee P and I only know
its t Then I can derive
the others yes Well it turns out it can yes only
the question is how much is the minimum quantity
that we have to know to derive the
other quantities so that is the
basis of thinking of the state postulate yes
because in a system there are
many characteristics but how much is the
minimum quantity that I have to
know to derive the
other quantities yes so the state postulate is the
state of a compressed system here there
is
a keyword yes that is compressed
meaning there are no forces yes
other forces such as e force yes what is the
fluid like is moving then there is an
electric force there is a magnetic force that does
cause imbalance that is
the definition of a compressed system yes it
can be described the state of the system
yes by two
mutually independent intensive properties so remember
intensive is a quantity that if I
divide the volume does not change which is mutually
independent Yes that is the requirement for eh
to obtain the state of
eh these two quantities they must be intensive
and mutually independent yes Well two
properties can be said to be independent if
one of the properties is changed the other
is kept constant yes that is an example
I want to know the
e property or quantity of a
system yes we know there is P there is V there is
t e and so on yes well I only
know two but the condition is that both
must be intensive and independent for
example P and t are both
intensive yes and
extensive Okay intensive and extensive
so I can increase the t so the
t is increased while
maintaining the value of p yes that is
the definition of independent so they do not
affect each other directly yes
like that yes For example if I
know P and t then I can decrease the
p yes or the volume by means of yes the
formula that we may have studied
together in high school namely yes the Boile G
lusak formula yes Where pv / t
= constant yes so that is the condition to
obtain the
ee magnitude of a state or
property of a state it must be
At least we must know two properties
that are intensive and independent yes that
is an example of ee from this yes Well
another example is P and specific
volume right volume yes so P
pressure pressure eh sorry It should not be P
and V yes they influence each other yes
So if P and V are not mutually
independent yes but the
other independent ones are ee these are not
mutually independent yes I forgot earlier they are not
mutually
independent yes why yes If I
increase p the v will also change yes
Well I mean additional examples
for intensive and independent ones
are t and speciesfic volume yes this is the
same yes I increase the t the
volume can still be maintained yes yes
For example I have a vessel yes
box or cylinder I heat it yes
but I keep the volume
unchanged so if it is Gas of course
it will start to heat yes but I can
keep the volume constant yes Until
a certain level of course before yes the limit
is damaged yes like that Well that
is the postulate of the state Okay Well
next there is something called a
process and cycle yes process and cycle
so this process is a change of a
system from an equilibrium state to
another equilibrium state for example yes Ee
if I have I will draw it first yes
I have two properties in ee one
or in the XY axis yes for example
this property 1 this property
du yes usually this property ee
volume This property of pressure yes ee
or vice versa yes yes can p can V yes
can p t yes and and and so on yes
Well ee if I draw it here yes
He has for example
P1 P1 then here there is P2 P2 yes
then he
ee processes Yes like this Well for example
curved yes then he can be straight
like this the change can be like this
yes There are many paths yes later we will
learn together it turns out that different paths
or what is called pet or
path Yes it can cause differences in the
characteristics of the system In this case
the work produced yes Well that will be
discussed later in the lecture or video
Next yes like that yes So this
is a state of equilibrium one this is
state 1 then it changes to
state
two yes like that yes So this is an example
yes so ee it is called a
process yes and a series of states Why is it
called a series of states because if
he is in the middle path Here he passes through
every equilibrium point Is that right or not
yes he passes through every ee
equilibrium point here The small ones yes
so that is a series of states that are
passed throughout the process namely path yes
this can be called path one path two
path 3 each of which passes through
processes or sor
small states like that Well then
there is one process that will be the assumption
of our discussion in thermodynamics,
namely the quasi-static process, yes Well this
needs understanding if it's your
first time hearing this, so the
quasi-static or quasi-balance process
is a very
slow process where the system can change
internally so that all
parts of the process in the system
change simultaneously, yes For example,
if I have a piston, let's say
the piston is facing to the right now, yes, it's a
little different, yes, here there is a limit that
can move,
yes, then I press it, yes, so when
I press the particle at the end
here, it will press, yes, the particle
here, maybe it will also
press there, yes, then the value of P, yes,
or the momentum of this particle, yes, or the
right of the wall here, yes,
between the particle and the wall, yes,
they change slowly, yes,
meaning the p changes, yes, then
each of the particles also
adjusts, yes,
so the process is slow,
not fast, so the p changes,
then the volume changes and they do
not overtake each other, yes, so that's the
difference between a fast process
or a fast process quasistatic yes so
every property that changes does not
precede each other so One of the
properties changes yes internally
the system adjusts to the
other properties yes For example I
enlarge this image yes if this is
from this one state to the
second state yes then there is a process
Let's say straight yes so it's easy
this is the process yes Well Is
n't in every process This
direction is probably here yes Isn't in
every process we have
small states yes Let
's say state 1A 1B and so on yes Well in
every state of course
it
has properties too it has P P and
t also here is also the same it has P
P and t also yes well every Quantity
changes yes for example yes this p p accent this
P accent accent accent Dou accent Dou accent
yes it changes yes but they do not precede each other
yes Nothing is faster
than the other yes So when
the pressure changes the volume also
changes the t also t also
changes yes Well this process is an
assumptive process yes or assumption yes
which in real life eh
we don't encounter much but in terms of
eh static brush process that is in
thermodynamics we use the
assumptions, yes, for what to calculate
maximum efficiency, we will
learn later in the next chapters, yes,
for example, some types of processes that
we may have learned
in high school, there is something called
isothermal, namely constant t, isohoric, namely
constant v, yes, there is something
called isobaric or
constant p, yes, or adiabatic, yes, So there
is no exchange or no change
in heat, yes, So there is no heat
flowing, yes, like that, yes, so it
is an isothermal, isohoric,
isobaric and
adiabatic process, yes, okay, yes, like that, yes, then
this is what we will probably
learn throughout this course, yes,
then what is related to the
process is a cycle, yes, a cycle
is a system that goes
through a series of
processes, yes, whose condition returns to its
original state, yes, So if I make it
again here, the
x-axis is usually P, the y-axis is
usually P, yes, Uh, pressure and
volume, yes, for example, the first state,
then it moves to the second state, then it moves
to the third state, yes,
then it moves again, back
to the state that was first Yes, this is
called a cycle, yes, this is the
first process, then it tilts a little bit, the
second process, yes, then it comes back
here, up Sorry, we're back
to it, I'll make a new line, yes,
like this, yes, So this is what is called a
cycle, ee, cycle, cycle, yes, so one, second, two, third,
three,
back to one, yes, this is called a
cycle, yes, later we will
also learn a lot of thermodynamic cycles,
yes, which are indeed the characteristics of
several applications or engines that
we will learn, such as the
steam engine cycle, then the ee, ee,
refrigeration cycle, yes, those are examples of
cycles that we will learn
later, okay, now, ee, this is the
last part, namely the zeroth law of
thermodynamics, yes, so the Zeroth Law of
Thermodynamics is interesting, yes, why is
there a zeroth law? Yes, because there is the
first law, then there is the second law that
we discussed in the
previous slide, yes, why is there a
zeroth law, it turns out that this zeroth law was
discovered, maybe not discovered, yes,
formulated by scientists, yes,
long after the first law and the
second law, yes, so
ee, so far, yes, even em, because
far away, yes, it's been 50 years, yes,
So almost half a century, the first law
already exists, the second law already exists, eh,
it turns out there is a zeroth law which is
considered much more fundamental
than law 1 and law 2, that's why it's
called the zeroth law Yes, like
that Well, this zeroth law speaks or
has a definition or has a formulation, ee
ee, so if there are two objects that are in
thermal equilibrium with a third object,
then the two objects are in
thermal equilibrium, yes, for example, ee, if I
have one object, for example, a box
like this, then I have another object, yes,
Okay, I have another one, for example, this B,
this B,
yes, then this one is a, yes,
then a and b are in equilibrium with
object C, yes, weigh it with object C, yes,
I make
another box, yes, more or less like this, yes, this
is C, yes, So if
a If A and C are in
thermal equilibrium, it means the temperature is the same, right,
then B and C are in thermal equilibrium
too, yes,
then a and b are in
thermal equilibrium Well, maybe you think up to
here, yes, Oh yes, ten That's all If A
and C are the same temperature or
thermal equilibrium B and C are thermal equilibrium well
obviously A and thermal equilibrium base Well
why should it be formulated Well that's the
importance there is one ee law yes there is
one phenomenon that is more
fundamental yes which indeed It
seems natural yes
but they call it the
people call it the law of Keol
yes Well the concept of temperature is actually
related to the law of Keol yes
in its application the concept of temperature or
temperature measuring instrument is two objects
in a state of thermal equilibrium if
both objects have the
same temperature yes maybe you also think
here yes yes yes yes yes if I have
two objects eh thermal equilibrium both
have the same temperature yes but that
is the first way of thinking that
humans can measure temperature
using one tool yes So if I
have one ee object yes then I
dip the thermometer yes then
this thermometer will start measuring yes with
its scale t for example in degrees
Celsius yes then I can know
the temperature of eh this substance yes or
system
by looking at the temperature of the
thermometer yes And they are made or yes
Legally Oh this thermodynamics ee the
thermometer has the
same temperature as the system yes
Therefore the temperature measurement that
we have been doing is
one of the applications of ee the Zeroth Law of
Thermodynamics yes yes even though this
looks ee simple yes but it must be
understood that ee this is
one of the ee laws that is indeed important Yes
because it is so important ee was discovered long
after law 1 and law 2 so it
is called the zeroth law of thermodynamics yes
okay that's all for today's lecture ee
in this video I mean and EE
Hopefully all my friends or anyone
who watches this video can also
understand the basic concepts of vocabulary and also
many terms in thermodynamics Okay see
you in lecture or in the next video
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